Laboratory of solid-state chemical reactions

Laboratory of solid-state chemical reactions

Нead of laboratory

Zelenetskii

Dr.Sci. in Chemistry, professor
Alexandr Zelenetskii

tel. +7 (495) 332-58-73
e-mail: anzel {at} ispm.ru

Research activity

Research activity of the Laboratory of solid-state chemical reactions includes conducting research in the field of solid-state chemical reactions.

Staff                                      

Chief scientific officer:
Alexandr Zelenetskii 

Leading researchers:
Tatyana Akopova 

Senior research scientists:
Tatyana Demina 
Sergei Uspenskii

Research fellows:
Marina Sizova
Georgiy Cherkaev

Junior researchers:
Muhammed Havpachev
Pavel Ivanov
Polina Khaptahanova
Natalya Svishcheva

Graduate students:
Polina Khaptahanova
Natalya Svishcheva

Group of solid-phase chemical processes under pulsed mechanical action

Leading researchers:
Alexey Alexandrov

Senior research scientist:
Ivan Alexandrov

Research fellows:
Irina Metlenkova

Main publications overview

2018

Polycomplexes of Hyaluronic Acid and Borates in a Solid State and Solution: Synthesis, Characterization and Perspectives of Application in Boron Neutron Capture Therapy

A. N. Zelenetskii, S. Uspenskii, A.Zaboronok, G. Cherkaev, A. Shchegolihin, B. J. Mathis, M. Selyanin, T. Yamamoto, A. Matsumura 

Polymers , 2018, 181; DOI: 10.3390/polym10020181

A new method of synthesis of substituted 1-(1H-imidazole-4-yl)-1H-1,2,3-triazoles and their fungicidal activity

M.V. Dubovis, G.F. Rudakov, A.S. Kulagin, K.V. Tsarkova, S.V. Popkov, A.S. Goloveshkin, Georgiy V. Cherkaev 

Tetrahedron, 2018, 672-683 ; DOI: 10.1016/j.tet.2017.12.043

Multiferroic: A Polymer Composite Based on Organometallic Cobalt Dimers with Dzyaloshinskii–Moriya Effect

A. I. Aleksandrov, V. G. Shevchenko, I. A. Aleksandrov

Polymer Science, Series A, 2018, 74–80 ; DOI: 10.1134/S0965545X18010017

Preparation of poly(L,L-lactide) microparticles via Pickering emulsions using chitin nanocrystals

T. Demina, Y.Sotnikova, A. Istomin, C. Grandfils, T.Akopova, A. Zelenetskii 

Advances in Materials Science and Engineering, 2018, 8518016; DOI: 10.1155/2018/8518016

Influence of liquid media on the craze initiation in amorphous polylactide

E.S. Trofimchuk, N.I. Nikonorova, M.A. Moskvina, A.V. Efimov, M.A. Khavpachev, A.L. Volynskii

Polymer, 2018, 43-47; DOI: 10.1016/j.polymer.2018.03.023

Sodiumoxy (aminopropyl) alkoxysilanes-AB2 type monomers for the synthesis of hyperbranched poly (aminopropyl) alkoxysiloxanes and their derivatives

D. Migulin, S. Milenin, G. Cherkaev, E. Svidchenko, N. Surin, A. Muzafarov 

Journal of Organometallic Chemistry, 2018, 24-32; DOI: 10.1016/j.jorganchem.2017.11.028

2017

Macroporous hydrogels based on chitosan derivatives: preparation, characterization and in vitro evaluation

T.S. Demina, D.S. Zaytseva-Zotova, T.A. Akopova, A.N. Zelenetskii, E.A. Markvicheva 

Journal of Applied Polymer Science, 2017, 44651; DOI: 10.1002/app.44651

Two-Photon-Induced Microstereolithography of Chitosan-g-Oligolactides as a Function of Their Stereochemical Composition

T.S. Demina, K.N. Bardakova, N.V. Minaev, E.A. Svidchenko, A.V. Istomin, G.P. Goncharuk, L.V. Vladimirov, A.V. Grachev, A.N. Zelenetskii, P.S. Timashev, T.A. Akopova 

Polymers , 2017, 302; DOI: 10.3390/polym9070302

Materials based on guar and hydroxypropylguar filled with nanocrystalline polysaccharides

 Y.S. Sotnikova, T.S. Demina, A.V. Istomin, E.A. Svidchenko, E.N. Subcheva, N.M. Surin, N.A. Akopova, A.N. Zelenetskii 

Fibre Chemistry, 2017, 188-194 ; DOI: 10.1007/s10692-017-9867-x

Transport of the Colloid Matter of Riverine Runoff through Estuaries

E.V. Lasareva, A.M. Parfenova, T.S. Demina, N.D. Romanova, N.A. Belyaev, E.A. Romankevich

Oceanology, 2017, 520–529; DOI: 10.1134/S0001437017040130

Application of High-Energy Chemistry Methods to the Modification of the Structure and Properties of Polylactide (A Review)

T.S. Demina, A.B. Gilman, A.N. Zelenetskii

High Energy Chemistry, 2017, 302-314 ; DOI: 10.1134/S0018143917040038

A Biocompatible Nanocomposite Based on Allyl Chitosan and Vinyltriethoxysilane for Tissue Engineering

A.I. Aleksandrov, T.A. Akopova, V.G. Shevchenko, G.V. Cherkaev, E.N. Degtyarev, A.A. Dubinskii, V.G. Krasovskii, A.I. Prokof'ev, S.S. Abramchuk, M.I. Buzin

Polymer Science, Series B, 2017, 97-108; DOI: 10.1134/S1560090417010018

Complexes of CuCl2 with low generation dendrimer G1-4S-Bu. Density functional calculations of structure and physicochemical properties

 A.I. Alexandrov,  A.N. Tarasenkov ,  I.A. Alexandrov, I.Y. Metlenkova, S.S. Kisilev, Y.A. Borisov 

Russian Chemical Bulletin, 2017, 813-820;

Available on elibrary.ru

The Suzuki modification of functional polydimethylsiloxanes

F.V. Drozdov, G.V. Cherkaev, A.M. Muzafarov

Mendeleev Communications, 2017, 571-572; DOI: 10.1016/j.mencom.2017.11.010

2016

Synthesis of the first hyperbranched polyorganoethoxysilsesquioxanes and their chemical transformations to functional core-shell nanogel systems

D. Migulin, E. Tatarinova, I. Meshkov, G. Cherkaev, N. Vasilenko, M. Buzin, A. Muzafarov

Polymer International, 2016, 72 – 83; DOI: 10.1002/pi.5029

Polylactide-based microspheres prepared using solid-state copolymerized chitosan and D,L-lactide

T.S. Demina, T.A. Akopova, L.V. Vladimirov, A.N. Zelenetskii, E.A. Markvicheva, Ch. Grandfils

Materials Science and Engineering C, 2016, 333-338; DOI: 10.1016/j.msec.2015.09.094

Chitosan impregnation with biologically active tryaryl imidazoles in supercritical carbon dioxide

A. V. Cherkasova, N. N. Glagolev, A. I. Shienok, T. S. Demina, S. L. Kotova, N. L. Zaichenko, T. A. Akopova, P. S. Timashev, V. N. Bagratashvili, A. B. Solovieva

Journal of Materials Science: Materials in Medicine , 2016, 141; DOI: 10.1007/s10856-016-5753-y

Macroporous hydrogels based on chitosan derivatives: Preparation, characterization, and in vitro evaluation

T. S. Demina, D. S. Zaytseva-Zotova, T. A. Akopova, A. N. Zelenetskii, E. A. Markvicheva 

Journal of Applied Polymer Science , 2016; DOI: 10.1002/app.44651

Features of structures formation on the basis of chitosan derivatives by a prototype of 263 nm laser stereolithograph

D. S. Dudova, K. N. Bardakova, T. A. Akopova, P. S. Timashev, N. V. Minaev

IOP Conference Series: Journal of Physics , 2016, 12046; DOI: 10.1088/1742-6596/737/1/012046

Radio-Frequency Superradiance Induced by the Rheological Explosion of Polymer Composites Containing Paramagnetic Cobalt Complexes

A. I. Aleksandrov, I. A. Aleksandrov, S. B. Zezin, E. N. Degtyarev, A. A. Dubinskiy, S. S. Abramchuk, A. I. Prokof’ev

Russian Journal of Physical Chemistry B, 2016, 69-67; DOI: 10.1134/S1990793116010139

Molecular Structure and Morphology of Biomineral Composites Based on Nanohydroxyapatite and Hyaluronic Acid

 A.V. Severin,P.L. Ivanov , J.V. Kostina ,  T.P. Kalmykova,  S.V. Antonov, V.N. Khabarov 

Polymer Science, Series B , 2016, 428–438; DOI: 10.1134/S1560090416040060

A study of the viscosity of hyaluronic acid solutions for the preparation of polyelectrolyte complexes with chitosan

S.A. Uspenskii , T.S. Demina ,  N.R. Kil’deeva, M.V. Maslova , G.A. Vikhoreva 

Russian Chemical Bulletin, 2016, 273-276; DOI: 10.1007/s11172-016-1296-0

Multiferroic based on metal – organic dimers with the Dzyaloshinskii – Moriya effect

A. I. Aleksandrov, I. A. Aleksandrov, V.G. Shevchenko

JETP Letters, 2016, 568 – 572; DOI: 10.1134/S0021364016200066

Compatibility of Cells of the Nervous System with Structured Biodegradable Chitosan-Based Hydrogel Matrices

P. S. Timashev, K. N. Bardakova, N. V. Minaev, T. S. Demina, T. A. Mishchenko, E. V. Mitroshina, A. A. Akovantseva, A. V. Koroleva, D. S. Asyutin, L. F. Pimenova, N. A. Konovalov, T. A. Akopova, A. B. Solov’eva, I. V. Mukhina, M. V. Vedunova, B. N. Chichkov, V. N. Bagratashvilі

Applied Biochemistry and Microbiology, 2016, 508-514; DOI: 10.1134/S0003683816050161

Fabrication of Microstructured Materials Based on Chitosan and D,L-Lactide Copolymers Using Laser-Induced Microstereolithography

T. S. Demina, K. N. Bardakova, E. A. Svidchenko, N. V. Minaev, G. I. Pudovkina, M. M. Novikov, D. V. Butnaru, N. M. Surin, T. A. Akopova, V. N. Bagratashvili, A. N. Zelenetskii, P. S. Timashev

High Energy Chemistry, 2016, 389–394; DOI: 10.1134/S0018143916050088

Biodegradable scaffolds based on chitosan: preparation, properties, and use for the cultivation of animal cells

N.R. Kil’deeva, M.A. Kasatkina, M.G. Drozdova, T.S. Demina, S.A. Uspenskii, S.N. Mikhailov, E.A. Markvicheva

Applied Biochemistry and Microbiology, 2016, 515-524; DOI: 10.1134/S0003683816050094

Nanocrystalline cellulose from flax stalks: preparation, structure, and use

A.V. Istomin, T.S. Demina, E.N. Subcheva, T.A. Akopova, A.N. Zelenetskii

Fibre Chemistry, 2016, 199-201; DOI: 10.1007/s10692-016-9767-5

Surgical sutures modified with polysaccharide compositions

Maslova M.V., Uspenskii S.A., Gal’braikh L.S., Kil’deeva N.R.

Fibre Chemistry, 2016, 253-257; DOI: 10.1007/s10692-016-9779-1

Acyclic polyphenylsilsesquioxane: synthesis and properties

M. N. Temnikov, M. I. Buzin, N. V.Demchenko, G. V. Cherkaev, N. G. Vasilenko, A. M. Muzafarov

Mendeleev Communications, 2016, 121-123; DOI: 10.1016/j.mencom.2016.03.012

Development of a method for introducing 1-aminophosphonate fragment in a siloxane matrix

R. R. Khairova, S. A. Milenin, G. V Cherkaev, I. I. Stoikov, A. M. Muzafarov  

Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 1617-1618; DOI: 10.1080/10426507.2016.1217218

Synthesis, Characterization, and Investigation of Thermosensitive Star-Shaped Poly (2-isopropyl-2-oxazolines) Based on Carbosilane Dendrimers

A. Amirova, S. Rodchenko, Z. Makhmudova, G. Cherkaev, S. Milenin, E. Tatarinova, M. Kurlykin, A. Tenkovtsev, A. Filippov

Macromolecular Chamistry and Physics, 2016, 1600387; DOI: 10.1002/macp.201600387

Star-shaped D–pi–A oligothiophenes with a tris(2-methoxyphenyl)amine core and alkyldicyanovinyl groups: synthesis and physical and photovoltaic properties

Y.N. Luponosov, J. Min, A.N. Solodukhin, A.V. Bakirov, P.V. Dmitryakov, M.A. Shcherbina, S.M. Peregudova, G.V. Cherkaev, S.N. Chvalun, C.J. Brabec, S.A. Ponomarenko 

Journal of Material Chemistry , 2016, 7061–7076; DOI: 10.1039/C6TC01530A

Study of a pure CsI crystal readout by APD for Belle II end cap ECL upgrade

Y. Jin, H. Aihara, O.V. Borshchev, D.A. Epifanov, S.A. Ponomarenko, N.M. Surin

Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2016, 691–692; DOI: 10.1016/j.nima.2015.07.034

2015

Synthesis and photovoltaic effect in red/near-IR absorbing A-D-A-D-A-type oligothiophenes containing benzothiadiazole and thienothiadiazole central units

Y. N. Luponosov, J. Min, D. A. Khanin, D. Baran, S. M. Peregudova, P.V. Dmitryakov, S. N. Chvalun, G. V. Cherkaev, E. A. Svidchenko, T. Ameri, C.J. Brabec, S. A. Ponomarenko 

Journal of Photonics for Energy , 2015; DOI: 10.1117/1.JPE.5.057213

Solid-state synthesis of unsaturated chitosan derivatives to design 3D structures through two-photon-induced polymerization

T.A. Akopova, P. S. Timashev, T. S. Demina, K. N. Bardakova, N. V. Minaev, V. F. Burdukovskii,, G.V. Cherkaev, L. V. Vladimirov, A. V. Istomin, E. A. Svidchenko, N. M. Surin, V. N. Bagratashvili

Mendeleev Communications , 2015, 280–282; DOI: 10.1016/j.mencom.2015.07.017

Optical properties of TiO2 thin films

Y.M. Evtushenko, S.V. Romashkin, N.S. Trofimov, T.K. Chekhlova 

Physics procedia, 2015, 100-107; DOI: 10.1016/j.phpro.2015.09.128

Solid state synthesis of chitosan and its unsaturated derivatives for laser microfabrication of 3D scaffolds

T. A. Akopova, T. S. Demina, V. N. Bagratashvili, K. N. Bardakova, M. M. Novikov, I. I. Selezneva, A. V. Istomin, E. A. Svidchenko, G. V. Cherkaev, N. M. Surin, P. S. Timashev

IOP Conference Series: Materials Science and Engineering , 2015, 12079; DOI: 10.1088/1757-899X/87/1/012079

Chitosan-g-lactide copolymers for fabrication of 3D scaffolds for tissue engineering

T. S. Demina, D. S. Zaytseva-Zotova, P. S. Timashev, V. N. Bagratashvili, K. N. Bardakova, Ch. Sevrin, E. A. Svidchenko, N. M. Surin, E. A. Markvicheva, Ch. Grandfils, T. A. Akopova

IOP Conference Series: Materials Science and Engineering , 2015, 12074; DOI: 10.1088/1757-899X/87/1/012074

Solid-state synthesis of unsaturated chitosan derivatives to design 3D structures through two-photon-induced polymerization

T. A. Akopova, P. S. Timashev, T. S. Demina, K. N. Bardakova, N. V. Minaev, V. F. Burdukovskii, G. V. Cherkaev, L. V. Vladimirov, A. V. Istomin, E. A. Svidchenko, N. M. Surin, V. N. Bagratashvili 

Mendeleev Communications, 2015, 280-282; DOI: 10.1016/j.mencom.2015.07.017

Hyaluronic acid as a potential boron carrier for BNCT: Preliminary evaluation

A. Zaboronok, T. Yamamoto, K. Nakai, F. Yoshida, S. Uspenskii, M. Selyanin, A. Zelenetskii, A. Matsumura

Applied radiation and isotopes, 2015, 181–184; DOI: 10.1016/j.apradiso.2015.08.020

Vacuum deposition of chitosan thin films by electron beam spattering

T.S. Demina, M.Yu.Yablokov, A.B. Gil’man, A. I. Gai’dar, T.A. Akopova, A.N. Zelenetskii

High Energy Chemistry, 2015, 212-215; DOI: 10.1134/S0018143915030078

Fabrication of Microstructured Materials Based on Chitosan and Its Derivatives Using Two-Photon Polymerization

P. S. Timashev, T. S. Demina, N. V. Minaev, K. N. Bardakova, A. V. Koroleva, O. A. Kufelt, B. N. Chichkov, V. Ya. Panchenko, T. A. Akopova, V. N. Bagratashvili 

High Energy Chemistry, 2015, 300-303; DOI: 10.1134/S0018143915040177

Thermochemical transformations of polyacrylonitrile nanofibers prepared by needleless electrospinning

T.V. Druzhinina,  A.I. Sidorina, A.V. Istomin

Fibre Chemistry , 2015, 73-78; DOI: 10.1007/s10692-015-9640-y

Novel Biocompatible Material Based on Solid-State Modified Chitosan for Laser Stereolithography

P. S. Timashev, K. N. Bardakova, T. S. Demina, G. I. Pudovkina ,M. M. Novikov, M. A. Markov,  D. S. Asyutin, L. F. Pimenov,  E. A. Svidchenko, A. M. Ermakov

Modern Technologies in Medicine, 2015, 20-29; DOI: 10.17691/stm2015.7.3.03

2014

A novel supramolecular hyaluronan/polyborate systems for tumour treatment by boron neutron capture therapies

A.N. Zelenetskii, S.A., Uspenskii, P.L. Ivanov, V.N. Khabarov 

In book: News in Chemistry, Biochemistry and Biotechnology: State of the Art and Prospects of Development: Nova Science Publishers, 2014, 135-143;

Modification of the Chitosan Structure and Properties Using High Energy Chemistry Methods

T.S. Demina, A.B. Gil’man, T.A. Akopova, A.N. Zelenetskii

High Energy Chemistry, 2014, 293-302; DOI: 10.1134/S0018143914050063

Effect of Borax Additives on the Rheological Properties of Sodium Hyaluronate Aqueous Solutions

S.А. Dubrovskii, A.N. Zelenetskii, S.A. Uspenskii, V.N. Khabarov

Polymer Science, 2014, 205–210; DOI: 10.1134/S0965545X14020047

The study of hyaluronic acid compounds for neutron capture and photon activation therapies

S. N. Koryakin, V. A.Yadrovskaya, E. E. Beketov, E.V. Isaeva,S. E. Ulyanenko, S. A. Uspenskiy, V. N. Khabarov, M. A. Selyanin. 

Central European Journal of Biology, 2014, 922-930; DOI: 10.2478/s11535-014-0329-7

Nanostructured organosilicon luminophores and their application in highly efficient plastic scintillators

S.A. Ponomarenko, N.M. Surin, O.V. Borshchev, Y.N. Luponosov, D.Y. Akimov, I.S. Alexandrov, A.A. Burenkov, A.G. Kovalenko, V.N. Stekhanov, E.A. Kleymyuk, O.T. Gritsenko, G.V. Cherkaev, A.S. Kechek'yan, O.A. Serenko, A.M. Muzafarov

Scientific Reports , 2014, 6549; DOI: 10.1038/srep06549

2013

New surface-enhanced Raman scattering platforms: composite calcium carbonate microspheres coated with astralen and silver nanoparticles

I.Y. Stetciura, A.V. Markin, A.N. Ponomarev, A.V. Yakimansky, T.S. Demina, Ch. Grandfils, D.V. Volodkin, D.A. Gorin

Langmuir, 2013, 4140-4147; DOI: 10.1021/la305117t

Polymer-inorganic composite with ultradisperse gadolinium particles

Aleksandrov I.A., Metlenkova I.Y., Aleksandrov A.I., Abramchuk S.S., Solodovnikov S.P., Khodak A.A., Zezin S.B.

Technical Physics. The Russian Journal of Applied Physics, 2013, 375-379; DOI: 10.1134/S1063784213030031

Fracture of polystyrene- and molecular silica sol-based nanocomposites during fast compression

Aleksandrov I.A., Gritsenko O.T., Perov N.S., Getmanova E.V., Obolonkova E.S., Serenko O.A., Shevchenko V.G., Aleksandrov A.I., Muzafarov A.M.

Technical Physics. The Russian Journal of Applied Physics, 2013, 88 – 93; DOI: 10.1134/S1063784213010027

Synthesis and Characterization of Organo-Inorganic Nanoobjects Based on Hyperbranched Polyethoxysiloxanes

A.S. Zhiltsov, K.L. Boldyrev, O.B. Gorbatsevitch, V.V. Kazakova, N.V. Demchenko, G.V. Cherkaev, A.M. Muzafarov

Silicon, 2013, 165-176; DOI: 10.1007/s12633-014-9229-8